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Impact of non-reciprocal interactions on colloidal self-assembly with tunable anisotropy
Soft Condensed Matter · Submitted 18 Apr 2024
abstract compiled · 2026-09-23 · no language-model review
The authors' main claim Overall, NR interactions are shown to destabilize the rigid aggregates interrupting self-assembly in the passive case, helping the system to overcome kinetic barriers.
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The abstract, sentence by sentence
Non-reciprocal (NR) effective interactions violating Newton's third law occur in many biological systems, but can also be engineered in synthetic, colloidal systems. Recent research has shown that such NR interactions can have tremendous effects on the overall collective behaviour and pattern formation, but can also influence aggregation processes on the particle scale. Here we focus on the impact of non-reciprocity on the self-assembly of an (originally passive) colloidal system with anisotropic interactions whose character is tunable by external fields. In the absence of non-reciprocity, that is, under equilibrium conditions, the colloids form aggregates with extremely long life times [Kogler et al., Soft Matter 11, 7356 (2015)], indicating kinetic trapping. Here we study, based on Brownian Dynamics (BD) simulations in 2D, a NR version of this model consisting of two species with reciprocal isotropic, but NR anisotropic interactions. We find that NR induces an effective propulsion of particle pairs and small aggregates forming at initial stages of self-assembly, an indication of the NR-induced non-equilibrium. The shape and stability of these initial clusters strongly depends on the degree of anisotropy. At longer times we find, for weak NR interactions, large (even system-spanning) clusters where single particles can escape and enter at the boundaries, in stark contrast to the small rigid aggregates appearing at the same time in the passive case. In this sense, weak NR shortcuts the aggregation. Increasing the degree of NR (and thus, propulsion), we even observe large-scale phase separation if the interactions are weakly anisotropic. In contrast, system with strong NR and anisotropy remain essentially disordered. Overall, NR interactions are shown to destabilize the rigid aggregates interrupting self-assembly in the passive case, helping the system to overcome kinetic barriers.
background contribution method result interpretation main claim
| # | sentence | role | the authors' own work | states the main conclusion | strength |
|---|---|---|---|---|---|
| s0 | Non-reciprocal (NR) effective interactions violating Newton's third law occur in many biological systems, but can also be engineered in synthetic, colloidal systems. | background 1.00 | 0.04 | 0.02 | asserted 0.99 |
| s1 | Recent research has shown that such NR interactions can have tremendous effects on the overall collective behaviour and pattern formation, but can also influence aggregation processes on the particle scale. | background 1.00 | 0.05 | 0.04 | asserted 0.84 |
| s2 | Here we focus on the impact of non-reciprocity on the self-assembly of an (originally passive) colloidal system with anisotropic interactions whose character is tunable by external fields. | contribution 0.98 | 0.41 | 0.04 | asserted 0.77 |
| s3 | In the absence of non-reciprocity, that is, under equilibrium conditions, the colloids form aggregates with extremely long life times [Kogler et al., Soft Matter 11, 7356 (2015)], indicating kinetic trapping. | background 0.93 | 0.11 | 0.03 | asserted 0.84 |
| s4 | Here we study, based on Brownian Dynamics (BD) simulations in 2D, a NR version of this model consisting of two species with reciprocal isotropic, but NR anisotropic interactions. | method 0.57 | 0.87 | 0.03 | asserted 0.97 |
| s5 | We find that NR induces an effective propulsion of particle pairs and small aggregates forming at initial stages of self-assembly, an indication of the NR-induced non-equilibrium. | result 0.98 | 0.96 | 0.13 | asserted 0.94 |
| s6 | The shape and stability of these initial clusters strongly depends on the degree of anisotropy. | result 1.00 | 0.89 | 0.04 | asserted 1.00 |
| s7 | At longer times we find, for weak NR interactions, large (even system-spanning) clusters where single particles can escape and enter at the boundaries, in stark contrast to the small rigid aggregates appearing at the same time in the passive case. | result 1.00 | 0.96 | 0.13 | asserted 1.00 |
| s8 | In this sense, weak NR shortcuts the aggregation. | interpretation 0.98 | 0.79 | 0.13 | asserted 0.99 |
| s9 | Increasing the degree of NR (and thus, propulsion), we even observe large-scale phase separation if the interactions are weakly anisotropic. | result 1.00 | 0.95 | 0.10 | asserted 0.99 |
| s10 | In contrast, system with strong NR and anisotropy remain essentially disordered. | result 1.00 | 0.92 | 0.09 | asserted 0.99 |
| s11 | Overall, NR interactions are shown to destabilize the rigid aggregates interrupting self-assembly in the passive case, helping the system to overcome kinetic barriers. | interpretation 0.93 | 0.91 | 0.90 | asserted 1.00 |
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Original abstract
Non-reciprocal (NR) effective interactions violating Newton's third law occur in many biological systems, but can also be engineered in synthetic, colloidal systems. Recent research has shown that such NR interactions can have tremendous effects on the overall collective behaviour and pattern formation, but can also influence aggregation processes on the particle scale. Here we focus on the impact of non-reciprocity on the self-assembly of an (originally passive) colloidal system with anisotropic interactions whose character is tunable by external fields. In the absence of non-reciprocity, that is, under equilibrium conditions, the colloids form aggregates with extremely long life times [Kogler et al., Soft Matter 11, 7356 (2015)], indicating kinetic trapping. Here we study, based on Brownian Dynamics (BD) simulations in 2D, a NR version of this model consisting of two species with reciprocal isotropic, but NR anisotropic interactions. We find that NR induces an effective propulsion of particle pairs and small aggregates forming at initial stages of self-assembly, an indication of the NR-induced non-equilibrium. The shape and stability of these initial clusters strongly depends on the degree of anisotropy. At longer times we find, for weak NR interactions, large (even system-spanning) clusters where single particles can escape and enter at the boundaries, in stark contrast to the small rigid aggregates appearing at the same time in the passive case. In this sense, weak NR shortcuts the aggregation. Increasing the degree of NR (and thus, propulsion), we even observe large-scale phase separation if the interactions are weakly anisotropic. In contrast, system with strong NR and anisotropy remain essentially disordered. Overall, NR interactions are shown to destabilize the rigid aggregates interrupting self-assembly in the passive case, helping the system to overcome kinetic barriers.
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