Optimal Waveforms for Dipole Moment Estimation with Coherent States

We investigate quantum sensing for spectroscopy in a system consisting of a two-level atom coupled to a continuum of modes. We focus on optimizing the pulse shape of a coherent state to maximize the quantum Fisher information (QFI) of the emitted light with the aim of estimating the atom's dipole moment, which is proportional to its spontaneous emission rate. To achieve this, we derive a set of coupled differential equations, which include the standard optical Bloch equations as a subset and whose solution directly yields the QFI of the emitted light without resorting to finite-difference methods. Furthermore, we analyze the factors that govern its optimization, provide analytic solutions in both the long and the short pulse width limits, and examine the role of the average photon number of the pulses. We then show that under the closed (periodic) boundary conditions, the harmonic (plane-wave) with frequency equal to half the spontaneous emission rate and a phase determined by detuning are optimal in the long pulse width limit.