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arxiv: 1407.5462 · v2 · pith:3H66HFVEnew · submitted 2014-07-21 · ❄️ cond-mat.soft · cond-mat.stat-mech

Hydrodynamic anomalies in supercritical fluid

classification ❄️ cond-mat.soft cond-mat.stat-mech
keywords fluidanomaliesdensityhydrodynamiclinessupercriticaltemperaturetime
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Using the molecular dynamics simulations we investigate properties of velocity autocorrelation function of Lennard-Jones fluid at long and intermediate time scales in wide ranges of temperature and density. We show that the amplitudes of the leading and subleading VAF time asymptotes, $a_1$ and $a_2$, show essentially non monotonous temperature and density dependence. There are two lines on temperature-density plain corresponding to maxima of $a_1$ ($a_2$) along isochors and isotherms situated in the supercritical fluid (hydrodynamic anomalies). These lines give insight into the stages of the fluid evolution into gas.

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