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Probability and Irreversibility in Modern Statistical Mechanics: Classical and Quantum

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arxiv 2104.11223 v1 pith:3XKZAZLO submitted 2021-04-22 cond-mat.stat-mech

Probability and Irreversibility in Modern Statistical Mechanics: Classical and Quantum

classification cond-mat.stat-mech
keywords probabilityirreversibilitymechanicsquantumexamplesstatisticalwideanalysis
verification ladder T0 review T1 audit T2 compute T3 formal T4 reserved
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Through extended consideration of two wide classes of case studies -- dilute gases and linear systems -- I explore the ways in which assumptions of probability and irreversibility occur in contemporary statistical mechanics, where the latter is understood as primarily concerned with the derivation of quantitative higher-level equations of motion, and only derivatively with underpinning the equilibrium concept in thermodynamics. I argue that at least in this wide class of examples, (i) irreversibility is introduced through a reasonably well-defined initial-state condition which does not precisely map onto those in the extant philosophical literature; (ii) probability is explicitly required both in the foundations and in the predictions of the theory. I then consider the same examples, as well as the more general context, in the light of quantum mechanics, and demonstrate that while the analysis of irreversibility is largely unaffected by quantum considerations, the notion of statistical-mechanical probability is entirely reduced to quantum-mechanical probability.

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Cited by 1 Pith paper

Reviewed papers in the Pith corpus that reference this work. Sorted by Pith novelty score.

  1. Derivation of the Boltzmann equation with no "molecular chaos"-type approximation

    cond-mat.stat-mech 2026-07 reject novelty 5.0

    A projection-operator derivation of closed kinetic equations that, despite its title, reintroduces a molecular-chaos-like assumption to obtain the nonlinear Boltzmann equation.