pith. sign in

arxiv: 1306.3866 · v2 · pith:6AKXPP3Jnew · submitted 2013-06-17 · ⚛️ physics.chem-ph · cond-mat.stat-mech

Efficiency at maximum power of a chemical engine

classification ⚛️ physics.chem-ph cond-mat.stat-mech
keywords chemicaldeltatransportparticlepowerconstantdifferenceefficiency
0
0 comments X p. Extension
pith:6AKXPP3J Add to your LaTeX paper What is a Pith Number?
\usepackage{pith}
\pithnumber{6AKXPP3J}

Prints a linked pith:6AKXPP3J badge after your title and writes the identifier into PDF metadata. Compiles on arXiv with no extra files. Learn more

read the original abstract

A cyclically operating chemical engine is considered that converts chemical energy into mechanical work. The working fluid is a gas of finite-sized spherical particles interacting through elastic hard collisions. For a generic transport law for particle uptake and release, the efficiency at maximum power $\eta$ takes the form 1/2+c\Delta \mu + O(\Delta \mu^2), with 1/2 a universal constant and $\Delta \mu$ the chemical potential difference between the particle reservoirs. The linear coefficient c is zero for engines featuring a so-called left/right symmetry or particle fluxes that are antisymmetric in the applied chemical potential difference. Remarkably, the leading constant in $\eta$ is non-universal with respect to an exceptional modification of the transport law. For a nonlinear transport model we obtain \eta = 1/(\theta +1), with \theta >0 the power of $\Delta \mu$ in the transport equation

This paper has not been read by Pith yet.

discussion (0)

Sign in with ORCID, Apple, or X to comment. Anyone can read and Pith papers without signing in.

Forward citations

Cited by 1 Pith paper

Reviewed papers in the Pith corpus that reference this work. Sorted by Pith novelty score.

  1. An Information-Theoretic Bound on Thermodynamic Efficiency and the Generalized Carnot's Theorem

    quant-ph 2026-04 unverdicted novelty 6.0

    A new bound based on state-Hamiltonian correlations gives the exact maximum efficiency for multi-bath thermal engines and is achievable beyond the quasistatic regime in a quantum dot model.