Dissociative ionization of H₂^+: Few-cycle effect in the joint electron-ion energy spectrum

Joint electron-ion energy spectra for the dissociative ionization of a model H$_2^+$ in few-cycle, infrared laser pulses are calculated via the numerical ab initio solution of the time-dependent Schr\"odinger equation. A strong, pulse-dependent modulation of the ionization probability for certain values of the protons' kinetic energy (but almost independent of the electron's energy) is observed. With the help of models with frozen ions, this feature---which mistakenly might be attributed to vibrational excitations---is traced back to the transient population of electronically excited states, followed by ionization. This assertion is further corroborated employing a two-level model incorporating strong-field ionization from the excited state.