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arxiv: 2311.07353 · v3 · pith:7VTMRHUMnew · submitted 2023-11-13 · ❄️ cond-mat.supr-con · cond-mat.mtrl-sci· cond-mat.str-el

Superconductivity in pressurized trilayer La₄Ni₃O_{10-{δ}} single crystals

classification ❄️ cond-mat.supr-con cond-mat.mtrl-scicond-mat.str-el
keywords superconductivitybehaviorchargecouplingcrystalsdeltahigh-temperatureinterlayer
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The pursuit of discovering new high-temperature superconductors that diverge from the copper-based paradigm1-3 carries profound implications for elucidating mechanisms behind superconductivity and may also enable new applications4-8. Here, our investigation reveals that application of pressure effectively suppresses the spin and charge order in trilayer nickelate La4Ni3O10-{\delta} single crystals, leading to the emergence of superconductivity with a maximum critical temperature (Tc) of around 30 K at 69.0 GPa. The DC susceptibility measurements confirm a substantial diamagnetic response below Tc, indicating the presence of bulk superconductivity with a volume fraction exceeding 80%. In the normal state, we observe a "strange metal" behavior, characterized by a linear temperature-dependent resistance extending up to 300 K. Furthermore, the layer-dependent superconductivity observed hints at a unique interlayer coupling mechanism specific to nickelates, setting them apart from cuprates in this regard. Our findings provide crucial insights into the fundamental mechanisms underpinning superconductivity, while also introducing a new material platform to explore the intricate interplay between the spin/charge order, flat band structures, interlayer coupling, strange metal behavior and high-temperature superconductivity.

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