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Multiple exciton generation and giant external quantum efficiency in VO₂

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arxiv 2202.04909 v3 pith:CB55ITZ7 submitted 2022-02-10 cond-mat.mtrl-sci physics.app-ph

Multiple exciton generation and giant external quantum efficiency in VO₂

classification cond-mat.mtrl-sci physics.app-ph
keywords quantumcorrelatedefficiencyexcitonexternalgenerationgiantmultiple
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Multiple exciton generation (MEG) is a widely studied phenomenon in semiconductor nanocrystals and quantum dots wherein photo-excited carriers relax by generating additional electron-hole pairs. Here, we present the first experimental observation of MEG and the same leading to giant external quantum efficiency (EQE) in VO$_2$, a prototype strongly correlated material. By employing a photoexcitation (lamda ~ 488 nm) of ~ 4.2 times the bandgap, EQE in VO$_2$ is enhanced up to ~ 170 % at room temperature. Temperature dependent experiments exhibit the direct relation between MEG and strength of electron correlation and suggest that such a phenomenon could be exploited in large number of strongly correlated materials for high performance solar cell research in near future.

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