Pith. sign in

REVIEW

Not yet reviewed by Pith; the record is open.

This paper has not been read by Pith yet. Machine review is queued; the pith claim, tier, and objections will appear here once it completes.

SPECIMEN: schema-true, not a live event

T0 review · schema-true

One-sentence machine reading of the paper's core claim.

pith:XXXXXXXX · record.json · timestamp

arxiv 2507.06680 v1 pith:DJTJ2U4R submitted 2025-07-09 physics.atom-ph physics.atm-clusphysics.optics

Rotational coherences in O₂^+ following strong-field ionization

classification physics.atom-ph physics.atm-clusphysics.optics
keywords probestatesstateionizationstrong-fieldwavecouplingdistribution
verification ladder T0 review T1 audit T2 compute T3 formal T4 reserved
0 comments
read the original abstract

We investigate the wave packet that remains bound in the ground and excited cationic states of oxygen after strong-field ionization by an intense 800-nm pulse. Much weaker probe pulses (800 or 264 nm) are used to dissociate these still-bound cations. The momentum distribution of O$^+$ is measured as a function of pump-probe delay and Fourier-transformed to obtain kinetic-energy-dependent and rotational-state-resolved quantum beat spectra. The sub-cm$^{-1}$ resolution of the Fourier transform allows unambiguous identification of the electronic, vibrational, and rotational states populated by the pump and then dissociated by the probe. Although strong-field ionization is expected to populate the lower-lying $X^2\Pi_g$ and $a^4\Pi_u$ states more effectively than the $b^4\Sigma^{-}_g$ state, a wave packet in the $X^2\Pi_g$ state is seen only with the 264-nm probe and only weak signatures of the $a^4\Pi_u$ states are found with either probe. The experiment confirms the role of the resonant coupling between the $b^4\Sigma^{-}_g$ and $a^4\Pi_u$ states by the 800 nm pulses [Xue \textit{et al.}, Phys. Rev. A 97, 043409 (2018)] and reveals the importance of rovibrational excitation in determining the momentum distribution of the O$^+$ fragments. The strong $X^2\Pi_g$ state contribution observed with the 264-nm probe also shows the importance of resonant coupling in the probe pulse. The sub-cm$^{-1}$ resolution also resolves spin-orbit splitting in both the $X^2\Pi_g$ and $a^4\Pi_u$ state wave packets.

discussion (0)

Sign in with ORCID, Apple, or X to comment. Anyone can read and Pith papers without signing in.