Quantum Charge Fluctuations in a Superconducting Grain

We consider charge quantization in a small superconducting grain that is contacted by a normal-metal electrode and is controlled by a capacitively coupled gate. At zero temperature and zero conductance $G$ between the grain and the electrode, the charge $Q$ as a function of the gate voltage $V_g$ changes in steps. The step height is $e$ if $\Delta<E_c$, where $\Delta$ and $E_c$ are, respectively, the superconducting gap and the charging energy of the grain. Quantum charge fluctuations at finite conductance remove the discontinuity in the dependence of $Q$ on $V_g$ and lead to a finite step width $\propto G^2\Delta$. The resulting shape of the Coulomb blockade staircase is of a novel type. The grain charge is a continuous function of $V_g$ while the differential capacitance, $dQ/dV_g$, has discontinuities at certain values of the gate voltage. We determine analytically the shape of the Coulomb blockade staircase also at non-zero temperatures.