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Anisotropic superconductivity and unusually robust electronic critical field in single crystal La$_{7}$Ir$_{3}$

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arxiv 2111.09239 v2 pith:ECG65SXJ submitted 2021-11-17 cond-mat.supr-con cond-mat.mtrl-scicond-mat.str-el

classification cond-mat.supr-concond-mat.mtrl-scicond-mat.str-el
keywords criticalcrystalsfieldsinglesuperconductivitycapacityelectronicfields
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abstract

Polycrystalline La$_{7}$Ir$_{3}$ is reported to show superconductivity breaking time-reversal symmetry while also having an isotropic $s$-wave gap. Single crystals of this noncentrosymmetric superconductor are highly desirable to understand the nature of the electron pairing mechanism in this system. Here we report the growth of high-quality single crystals of La$_{7}$Ir$_{3}$ by the Czochralski method. The structural and superconducting properties of these large crystals have been investigated using x-rays, magnetization, resistivity and heat capacity measurements. We observe a clear anisotropy in the lower and upper critical fields for magnetic fields applied parallel and perpendicular to the hexagonal $c$ axis. We also report the presence of a robust electronic critical field, that diverges from the upper critical field derived from heat capacity, which is the hallmark of surface superconductivity.

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