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arxiv: 1305.4246 · v1 · pith:G2SMBLEYnew · submitted 2013-05-18 · ⚛️ physics.chem-ph · cond-mat.soft

Scaling relation for the bond length, mass density, and packing order of water ice

classification ⚛️ physics.chem-ph cond-mat.soft
keywords waterbonddensitylengthmassorderpackingscaling
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The packing order of molecules and the distance between adjacent oxygen atoms (dOO) in water and ice are most basic yet puzzling. Here we present a scaling solution for this purpose based only on the mass density (gcm-3), (Equation) where dL is the length ({\AA}) of the O:H van der Waals bond and dH the H-O polar-covalent bond projecting on the O---O line. Validated by the measured proton symmetrization of compressed ice, dOO of water and ice, and dOO expansion at water surface, this solution confirms that the fluctuated, tetrahedrally-coordinated structure is unique for water ice.

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