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Stereodynamic control of overlapping resonances in cold molecular collisions

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arxiv 2005.06129 v1 pith:GWXR7AY2 submitted 2020-05-13 physics.chem-ph physics.atom-ph

Stereodynamic control of overlapping resonances in cold molecular collisions

classification physics.chem-ph physics.atom-ph
keywords coldcollisionscontrolmolecularoverlappingsystemsinteractingmolecule
verification ladder T0 review T1 audit T2 compute T3 formal T4 reserved
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Stereodynamic control of resonant molecular collisions has emerged as a new frontier in cold molecule research. Recent experimental studies have focused on weakly interacting molecular systems such as HD collisions with H$_2$, D$_2$ and He. We report here the possibility of such control in strongly interacting systems taking rotational relaxation in cold collisions of HCl and H$_2$. Using explicit quantum scattering calculations in full six dimensions it is shown that robust control of the collision dynamics is possible even when multiple (overlapping) shape-resonances coexist in a narrow energy range, indicating that cold stereochemistry offers great promise for many molecules beyond simple systems. We demonstrate a striking case where two prominent peaks in overlapping resonances are switched-off simultaneously by suitable alignment of the HCl molecule.

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