Pith. sign in

REVIEW

Thermodynamic stability of new phase Bi12.5Sm1.5ReO24.5

Not yet reviewed by Pith; the record is open.

Re-run · record.json Download PDF Read on arXiv ↗

This paper has not been read by Pith yet. Machine review is queued; the pith claim, tier, and objections will appear here once it completes.

SPECIMEN: schema-true, not a live event

T0 review · schema-true

One-sentence machine reading of the paper's core claim.

pith:XXXXXXXX · record.json · timestamp

arxiv 1307.5938 v1 pith:HLT3B7ZQ submitted 2013-07-23 cond-mat.mtrl-sci

Thermodynamic stability of new phase Bi12.5Sm1.5ReO24.5

N.I. Matskevich , Th. Wolf , A.N. Bryzgalova , T.I. Chupakhina , E.S. Zolotova , M.Yu. Matskevich , M.A. Bespytov This is my paper
classification cond-mat.mtrl-sci
keywords bi12reo24beenphasebi2o3re2o7above-mentionedbinary
verification ladder T0 review T1 audit T2 compute T3 formal T4 reserved
0 comments
Share X Bluesky LinkedIn Reddit HN
read the original abstract

The Bi12.5Sm1.5ReO24.5 phase has been synthesized for the first time. The preparation of Bi12.5Sm1.5ReO24.5 has been performed by solid-state reaction from Bi2O3, Gd2O3, Re2O7. The X-ray measurements have showed that Bi12.5Sm1.5ReO24.5 was cubic structure (space group Fm3m). The standard molar enthalpy of formation of Bi12.5Sm1.5ReO24.5 has been determined by solution calorimetry combining the enthalpies of dissolution of Bi12.5Sm1.5ReO24.5 and 6.25Bi2O3 + 0.75Sm2O3 + 0.5Re2O7 mixture in 2 M HCl and literature data. It has been obtained that above-mentioned phase is thermodynamically stable with respect to their decomposition into binary oxides at room temperatures.

discussion (0)

Sign in with ORCID, Apple, or X to comment. Anyone can read and Pith papers without signing in.