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arxiv 2101.06826 v1 pith:JT2XUWJV submitted 2021-01-18 cond-mat.mtrl-sci

Crossover from lamellar to spongy ice morphologies within a single ice crystal during unidirectional freezing of an aqueous solution

classification cond-mat.mtrl-sci
keywords aqueouscrystalsolutiongrowngrowthlamellarpatternsingle
verification ladder T0 review T1 audit T2 compute T3 formal T4 reserved
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Ice growth from liquid phase has been extensively investigated in various conditions, especially for ice freely grown in undercooled water and aqueous solutions. Although unidirectional ice growth plays a significant role in sea ice and freeze casting, the detailed pattern formation of unidirectionally grown ice in an aqueous solution remains elusive. For the first time, we in situ proved a crossover from lamellar to spongy ice morphologies of a single ice crystal via unidirectional freezing of an aqueous solution. The spongy ice morphology originates from the intersect of tilted lamellar ice and is observed in a single ice crystal, which is intrinsically different from the competitive growth of bi-crystal composed of two differently orientated grains in directional solidification. These results provide a complete physical picture of unidirectionally grown ice from aqueous solution and are believed to promote our understanding of various pattern of ice in many relevant domains where pattern formation of ice crystal is vital.

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