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Spatial Imaging of Land\'{e} g Factor through Extended Kondo Effect in a Single Magnetic Molecule

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arxiv 1310.8436 v1 pith:LEOQJ46J submitted 2013-10-31 cond-mat.mes-hall cond-mat.mtrl-sci

Liwei Liu , Yuhang Jiang , Boqun Song , Kai Yang , Wende Xiao , Shixuan Du , Min Ouyang , Werner A. Hofer
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Antonio. H. Castro Neto Hong-Jun Gao
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classification cond-mat.mes-hallcond-mat.mtrl-sci
keywords moleculefactorlandsingleatomicatomicallydehydrogenatedeffect
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A methodology of atomically resolved Land\'{e} g factor mapping of a single molecule is reported. Mn(II)-phthalocyanine (MnPc) molecules on Au(111) surface can be dehydrogenated via atomic manipulation with manifestation of tailored extended Kondo effect, which can allow atomically resolved imaging of the Land\'{e} g factor inside a molecule for the first time. By employing dehydrogenated MnPc molecules with removal of six H atoms (-6H-MnPc) as an example, Land\'{e} g factor of atomic constituents of the molecule can be obtained, therefore offering a unique g factor mapping of single molecule. Our results open up a new avenue to access local spin texture of a single molecule.

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