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Crystal structure and absence of magnetic order in single crystalline RuO$_2$

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arxiv 2410.05850 v1 pith:PMYGMVLQ submitted 2024-10-08 cond-mat.mtrl-sci

classification cond-mat.mtrl-sci
keywords structurediffractionantiferromagneticattributedcrystalcrystalsevidencemagnetic
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abstract

RuO$_2$ was considered for a long time to be a paramagnetic metal with an ideal rutile-type structure down to low temperatures, but recent studies on single-crystals claimed evidence for antiferromagnetic order and some symmetry breaking in the crystal structure. We have grown single-crystals of RuO2 by vapor transport using either O$_2$ or TeCl$_4$ as transport medium. These crystals exhibit metallic behavior following a $T^2$ low-temperature relation and a small paramagnetic susceptibility that can be attributed to Pauli paramagnetism. Neither the conductance nor the susceptibility measurements yield any evidence for a magnetic or a structural transition between 300K and $\sim$4 K. Comprehensive single-crystal diffraction studies with neutron and X-ray radiation reveal the rutile structure to persist until 2K in our crystals, and show nearly perfect stoichiometry. Previous observations of symmetry forbidden reflections can be attributed to multiple diffraction. Polarized single-crystal neutron diffraction experiments at 1.6K exclude the proposed antiferromagnetic structures with ordered moments larger than 0.01 Bohr magnetons.

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Cited by 2 Pith papers

Reviewed papers in the Pith corpus that reference this work. Sorted by Pith novelty score. Full citation record

  1. Effects of altermagnetic order, strain and doping in RuO$_2$

    cond-mat.mtrl-sci 2025-02 conditional novelty 6.0 of 10

    Optical reflectance, ellipsometry, and Raman data plus DFT indicate bulk RuO2 is best described as nonmagnetic, with altermagnetic order only potentially stabilized by specific epitaxial strain.

  2. Confinement-induced altermangetism in RuO$_2$ thin films

    cond-mat.mtrl-sci 2024-12 conditional novelty 6.0 of 10

    RuO2 thin films are predicted to be altermagnetic at zero Hubbard U due to interlayer relaxation, unlike bulk RuO2.

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