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We utilize a hybrid approach that integrates the traditional cross-correlation function (CCF) and machine learning to detect spectroscopic multi-systems, specifically focusing on double-line spectroscopic binary (SB2). Based on the ninth data release (DR9) of the Large Sky Area Multi-Object Fiber Spectroscopic Telescope (LAMOST), which includes a medium-resolution survey (MRS) containing 29,920,588 spectra, we identify 27,164 double-line and 3124 triple-line spectra, corresponding to 7096 SB2 candidates and 1903 triple-line spectroscopic binary (SB3) candidates, respectively, representing about 1% of the selection dataset from LAMOST-MRS DR9. Notably, 70.1% of the SB2 candidates and 89.6% of the SB3 candidates are newly identified. Compared to using only the traditional CCF technique, our method significantly improves the efficiency of detecting SB2, saves time on visual inspections by a factor of four.