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Correlation decoupling of Casimir interaction in an electrolyte driven by external electric fields

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arxiv 2404.06028 v2 pith:RE5YJYKA submitted 2024-04-09 cond-mat.stat-mech cond-mat.soft

classification cond-mat.stat-mechcond-mat.soft
keywords interactioncasimirelectrolytefieldslongthermalapplieddecoupling
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abstract

It has been established for a long time that the long range van der Waals or thermal Casimir interaction between two semi-infinite dielectrics separated by a distance $H$ is screened by an intervening electrolyte. Here we show how this interaction is modified when an electric field of strength $E$ is applied parallel to the dielectric boundaries, leading to a non-equilibrium steady state with a current. The presence of the field induces a long range thermal repulsive interaction, scaling just like the thermal Casimir interaction between dielectrics without the intervening electrolyte, {\em i.e.} as $1/H^3$. At small $E$ the effect is of order $E^2$ while at large fields it saturates to an $E$ independent value. We explain the results in terms of a decoupling mechanism between the charge density fluctuations of cations and anions at large applied fields.

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Cited by 2 Pith papers

Reviewed papers in the Pith corpus that reference this work. Sorted by Pith novelty score. Full citation record

  1. Stationary and transient correlations in driven electrolytes

    cond-mat.stat-mech 2024-11 conditional novelty 7.0 of 10

    In a driven symmetric electrolyte, ion density correlations form a universal conical long-range shape and relax diffusively after a field quench, explaining the algebraic relaxation of the current.

  2. The Dean-Kawasaki equation and stochastic density functional theory

    cond-mat.soft 2024-11 accept novelty 2.0 of 10

    A review of the Dean-Kawasaki equation and stochastic density functional theory, covering derivation, mathematical issues, extensions, solution methods, and applications.

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