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In this work we demonstrate how a lack of synchronization can in fact be advantageous in the problem of random access. Specifically, we consider a multiple-access problem over a frame-asynchronous 2-user binary-input adder channel in the unsourced setup (2-UBAC). Previous work has shown that under perfect synchronization the per-user rates achievable with linear codes over the 2-UBAC are limited by 0.5 bit per channel use (compared to the capacity of 0.75). In this paper, we first demonstrate that arbitrary small (even single-bit) shift between the user's frames enables (random) linear codes to attain full capacity of 0.75 bit/user. Furthermore, we derive density evolution equations for irregular LDPC codes, and prove (via concentration arguments) that they correctly track the asymptotic bit-error rate of a BP decoder. Optimizing the degree distributions we construct LDPC codes achieving per-user rates of 0.73 bit per channel use.