Metastability of Mn³⁺ in ZnO driven by strong d(Mn) intrashell Coulomb repulsion: experiment and theory

Depopulation of the Mn$^{2+}$ state in ZnO:Mn upon illumination, monitored by quenching of the Mn$^{2+}$ EPR signal intensity, was observed at temperatures below 80~K. Mn$^{2+}$ photoquenching is shown to result from the Mn$^{2+}$ $\to$ Mn$^{3+}$ ionization transition, promoting one electron to the conduction band. Temperature dependence of this process indicates the existence of an energy barrier for electron recapture of the order of 1~meV. GGA$+U$ calculations show that after ionization of Mn$^{2+}$ a moderate breathing lattice relaxation in the 3+ charge state occurs, which increases energies of $d$(Mn) levels. At its equilibrium atomic configuration, Mn$^{3+}$ is metastable since the direct capture of photo-electron is not possible. The metastability is mainly driven by the strong intra-shell Coulomb repulsion between $d$(Mn) electrons. Both the estimated barrier for electron capture and the photoionization energy are in good agreement with the experimental values.