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arxiv: 1403.0176 · v3 · pith:VWVCWHSBnew · submitted 2014-03-02 · ❄️ cond-mat.soft · cond-mat.mes-hall

Structure and phase transitions into ionic adsorption layers on liquid interfaces

classification ❄️ cond-mat.soft cond-mat.mes-hall
keywords adsorptionionicstructurelayerlayersliquidphasethermodynamic
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The structure of ionic adsorption layers is studied via a proper thermodynamic treatment of the electrostatic and non-electrostatic interactions between the surfactant ions as well as of the effect of thermodynamic non-locality. The analysis is also applied to phase transitions into the ionic adsorption layer, which interfere further with the oscillatory-diffusive structure of the electric double layer and hydrodynamic stability of squeezing waves in thin liquid films.

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