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arxiv: 1405.1647 · v4 · pith:X3HVTA6Gnew · submitted 2014-05-07 · 🧮 math-ph · math.FA· math.MP· quant-ph

Functional differentiability in time-dependent quantum mechanics

classification 🧮 math-ph math.FAmath.MPquant-ph
keywords time-dependentdifferentiabilitypotentialswaveechetfunctionfunctionallinear-response
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In this work we investigate the functional differentiability of the time-dependent many-body wave function and of derived quantities with respect to time-dependent potentials. For properly chosen Banach spaces of potentials and wave functions Fr\'echet differentiability is proven. From this follows an estimate for the difference of two solutions to the time-dependent Schr\"odinger equation that evolve under the influence of different potentials. Such results can be applied directly to the one-particle density and to bounded operators, and present a rigorous formulation of non-equilibrium linear-response theory where the usual Lehmann representation of the linear-response kernel is not valid. Further, the Fr\'echet differentiability of the wave function provides a new route towards proving basic properties of time-dependent density-functional theory.

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