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Magnetic structure determination of Ca₃LiOsO₆ using neutron and x-ray scattering

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arxiv 1206.1608 v1 pith:XR34NHMF submitted 2012-06-07 cond-mat.str-el cond-mat.mtrl-scicond-mat.other

Magnetic structure determination of Ca$_3$LiOsO$_6$ using neutron and x-ray scattering

classification cond-mat.str-el cond-mat.mtrl-scicond-mat.other
keywords magneticinteractionsuperexchangeextendedinvestigationinvolvingliosolong
verification ladder T0 review T1 audit T2 compute T3 formal T4 reserved
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abstract

We present a neutron and x-ray scattering investigation of Ca$_3$LiOsO$_6$, a material predicted to host magnetic ordering solely through an extended superexchange pathway involving two anions, an interaction mechanism that has undergone relatively little investigation. This contrasts with the ubiquitous superexchange interaction mechanism involving a single anion that has well defined and long standing rules. Despite the apparent 1D nature and triangular units of magnetic osmium ions the onset of magnetic correlations has been observed at a high temperature of 117 K in bulk measurements. We experimentally determine the magnetically ordered structure and show it to be long range and three dimensional. Our results support the model of extended superexchange interaction.

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