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arxiv: 1009.1102 · v1 · pith:Z3BNX2XUnew · submitted 2010-09-06 · ❄️ cond-mat.dis-nn · cond-mat.mes-hall· quant-ph

Excitons in Molecular Aggregates with L\'evy Disorder: Anomalous Localization and Exchange Broadening of Optical Spectra

classification ❄️ cond-mat.dis-nn cond-mat.mes-hallquant-ph
keywords disorderaggregatesbroadeningcollectivedistributionsexchangeexcitationsexcitons
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We predict the existence of exchange broadening of optical lineshapes in disordered molecular aggregates and a nonuniversal disorder scaling of the localization characteristics of the collective electronic excitations (excitons). These phenomena occur for heavy-tailed L\'evy disorder distributions with divergent second moments - distributions that play a role in many branches of physics. Our results sharply contrast with aggregate models commonly analyzed, where the second moment is finite. They bear a relevance for other types of collective excitations as well.

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