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Chemical functionalization of graphene

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arxiv 0809.5257 v2 pith:ZJFYDPDT submitted 2008-09-30 cond-mat.mtrl-sci

Chemical functionalization of graphene

classification cond-mat.mtrl-sci
keywords graphenefunctionalizationchemicalfluorinenanoribbonsstepacidcomplex
verification ladder T0 review T1 audit T2 compute T3 formal T4 reserved
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Experimental and theoretical results on chemical functionalization of graphene are reviewed. Using hydrogenated graphene as a model system, general principles of the chemical functionalization are formulated and discussed. It is shown that, as a rule, 100% coverage of graphene by complex functional groups (in contrast with hydrogen and fluorine) is unreachable. A possible destruction of graphene nanoribbons by fluorine is considered. The functionalization of infinite graphene and graphene nanoribbons by oxygen and by hydrofluoric acid is simulated step by step.

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