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arxiv: cond-mat/0201340 · v1 · submitted 2002-01-18 · ❄️ cond-mat.soft · cond-mat.stat-mech

Surface tension of liquids near the critical point

classification ❄️ cond-mat.soft cond-mat.stat-mech
keywords hamiltonianfluidgammaliquidsorderparametersurfacetension
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A simple analytical microscopic expression for the surface tension of liquids $\gamma$ is obtained which is in a good agreement with available data of numerical experiments. We apply the integral transformation that maps the fluid Hamiltonian onto the field-theoretical Hamiltonian and show that the order parameter of the effective Hamiltonian corresponds to the one-body potential in the fluid. Revealing the physical meaning of the order parameter allows calculation of $\gamma$.

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