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arxiv: cond-mat/0210354 · v1 · submitted 2002-10-16 · ❄️ cond-mat.soft · cond-mat.stat-mech

Microscopic theory for the glass transition in a system without static correlations

classification ❄️ cond-mat.soft cond-mat.stat-mech
keywords rodsconstantglasstransitioncorrelationsdiffusiondynamicsgamma
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We study the orientational dynamics of infinitely thin hard rods of length L, with the centers-of-mass fixed on a simple cubic lattice with lattice constant a.We approximate the influence of the surrounding rods onto dynamics of a pair of rods by introducing an effective rotational diffusion constant D(l),l=L/a. We get D(l) ~ [1-v(l)], where v(l) is given through an integral of a time-dependent torque-torque correlator of an isolated pair of rods. A glass transition occurs at l_c, if v(l_c)=1. We present a variational and a numerically exact evaluation of v(l).Close to l_c the diffusion constant decreases as D(l) ~ (l_c-l)^\gamma, with \gamma=1. Our approach predicts a glass transition in the absence of any static correlations, in contrast to present form of mode coupling theory.

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