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arxiv: cond-mat/0309315 · v1 · submitted 2003-09-12 · ❄️ cond-mat.soft · cond-mat.stat-mech

Validity of the scaling functional approach for polymer interfaces as a variational theory

classification ❄️ cond-mat.soft cond-mat.stat-mech
keywords approachtheorydescribefunctionalinterfacespolymerscalingtheories
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We discuss the soundness of the scaling functional (SF) approach proposed by Aubouy Guiselin and Raphael (Macromolecules 29, 7261 (1996)) to describe polymeric interfaces. In particular, we demonstrate that this approach is a variational theory. We emphasis the role of SF theory as an important link between ground-state theories suitable to describe adsorbed layers, and "classical" theories for polymer brushes.

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