Theoretical evidence for a reentrant phase diagram in {em ortho-para} mixtures of solid H₂
classification
❄️ cond-mat.stat-mech
cond-mat.mtrl-sci
keywords
orderphasesystemscorrelationfindformalismorientationalortho-para
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We develop a multi order parameter mean-field formalism for systems of coupled quantum rotors. The scheme is developed to account for systems where {\it ortho-para} distinction is valid. We apply our formalism to solid H$_2$ and D$_2$. We find an anomalous {\it reentrant} orientational phase transition for both systems at thermal equilibrium. The correlation functions of the order parameter indicate short-range order at low temperatures. As temperature is increased the correlation increases along the phase boundary. We also find that even extremely small {\it odd-J} concentrations (1%) can trigger short-range orientational ordering.
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