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arxiv: cond-mat/0509182 · v4 · submitted 2005-09-07 · ❄️ cond-mat.stat-mech · math-ph· math.MP

Rotational Brownian motion on the sphere surface and rotational relaxation

classification ❄️ cond-mat.stat-mech math-phmath.MP
keywords rotationalrelaxationbrownianmotionspheresurfaceanalyticallyautocorrelation
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The spatial components of the autocorrelation function of noninteracting dipoles are analytically obtained in terms of rotational Brownian motion on the surface of a unit sphere using multi-level jumping formalism based on Debye's rotational relaxation model, and the rotational relaxation functions are evaluated.

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