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arxiv: cond-mat/0703643 · v1 · submitted 2007-03-25 · ❄️ cond-mat.supr-con · cond-mat.mtrl-sci· cond-mat.str-el

Origin of superconductivity in nominally "undoped" T'-La_(2-x)Y_(x)CuO₄ films

classification ❄️ cond-mat.supr-con cond-mat.mtrl-scicond-mat.str-el
keywords filmsnominallysuperconductivityundopedcupratelycooriginphase
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We have systematically studied the transport properties of the La$_{2-x}$Y$_{x}$CuO$_{4}$(LYCO) films of T'-phase ($0.05\leq x \leq 0.30$). In this nominally "undoped" system, superconductivity was acquired in certain Y doping range ($0.10\leq x \leq 0.20$). Measurements of resistivity, Hall coefficients in normal states and resistive critical field ($H^\rho_{c2}$)in superconducting states of the T'-LYCO films show the similar behavior as the known Ce-doped n-type cuprate superconductors, indicating the intrinsic electron-doping nature. The charge carriers are induced by oxygen deficiency. Non-superconducting Y-doped Pr- or Nd-based T'-phase cuprate films were also investigated for comparison, suggesting the crucial role of the radii of A-site cations in the origin of superconductivity in the nominally "undoped" cuptates. Based on a reasonable scenario in the microscopic reduction process, we put forward a self-consistent interpretation of these experimental observations.

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