A tunable microscopic model of network liquids with a liquid-liquid phase transition, analyzed via RFOT theory, predicts nanonucleation near the glass transition and links thermodynamic and kinetic anomalies when matched to water-like conditions.
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The designed ternary liquid crystal mixture stabilizes a broad antiferroelectric SmC_A* phase, vitrifies the hexatic SmX_A* phase, and shows evidence of altered molecular organization between SmC* and SmC_A* phases based on X-ray, dielectric, and calorimetric data.
Ternary liquid crystal mixtures form glasses in the antiferroelectric smectic phase that selectively reflect blue light, with color in the ferroelectric phase depending on cooling or heating history.
Cooling rate controls whether 10OS5 forms glass or crystallizes into conformationally disordered Cr1/Cr2 phases whose cold-crystallization energy output can be tuned by thermal history.
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Selective reflection of light in glassforming ternary liquid crystalline mixtures
Ternary liquid crystal mixtures form glasses in the antiferroelectric smectic phase that selectively reflect blue light, with color in the ferroelectric phase depending on cooling or heating history.