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arxiv: 0711.3633 · v3 · pith:VNQTTEFTnew · submitted 2007-11-22 · ❄️ cond-mat.soft · cond-mat.stat-mech· physics.chem-ph

Depletion potential in the infinite dilution limit

classification ❄️ cond-mat.soft cond-mat.stat-mechphysics.chem-ph
keywords depletionhardhard-spherepotentialspheresagreementanalyzedapproximation
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The depletion force and depletion potential between two in principle unequal "big" hard spheres embedded in a multicomponent mixture of "small" hard spheres are computed using the Rational Function Approximation method for the structural properties of hard-sphere mixtures [S. B. Yuste, A. Santos, and M. L\'opez de Haro, J. Chem. Phys. {\bf 108}, 3683 (1998)]. The cases of equal solute particles and of one big particle and a hard planar wall in a background monodisperse hard-sphere fluid are explicitly analyzed. An improvement over the performance of the Percus-Yevick theory and good agreement with available simulation results are found

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