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arxiv: 0807.4465 · v2 · submitted 2008-07-28 · ❄️ cond-mat.stat-mech · cond-mat.dis-nn· cond-mat.mtrl-sci· cond-mat.soft

Solution of the Percus-Yevick equation for hard hyperspheres in even dimensions

classification ❄️ cond-mat.stat-mech cond-mat.dis-nncond-mat.mtrl-scicond-mat.soft
keywords dimensionsvirialalternatingbranchcharacterequationevenhard
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We solve the Percus-Yevick equation in even dimensions by reducing it to a set of simple integro-differential equations. This work generalizes an approach we developed previously for hard discs. We numerically obtain both the pair correlation function and the virial coefficients for a fluid of hyper-spheres in dimensions $d=4,6$ and 8, and find good agreement with available exact results and Monte-Carlo simulations. This paper confirms the alternating character of the virial series for $d \ge 6$, and provides the first evidence for an alternating character for $d=4$. Moreover, we show that this sign alternation is due to the existence of a branch point on the negative real axis. It is this branch point that determines the radius of convergence of the virial series, whose value we determine explicitly for $d=4,6,8$. Our results complement, and are consistent with, a recent study in odd dimensions [R.D. Rohrmann et al., J. Chem. Phys. 129, 014510 (2008)].

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