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arxiv: 0903.3877 · v3 · submitted 2009-03-23 · ❄️ cond-mat.soft · cond-mat.stat-mech· physics.chem-ph

A branch-point approximant for the equation of state of hard spheres

classification ❄️ cond-mat.soft cond-mat.stat-mechphysics.chem-ph
keywords statevirialequationaccuratebranch-pointcoefficientsconvergenceequations
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Using the first seven known virial coefficients and forcing it to possess two branch-point singularities, a new equation of state for the hard-sphere fluid is proposed. This equation of state predicts accurate values of the higher virial coefficients, a radius of convergence smaller than the close-packing value, and it is as accurate as the rescaled virial expansion and better than the Pad\'e [3/3] equations of state. Consequences regarding the convergence properties of the virial series and the use of similar equations of state for hard-core fluids in $d$ dimensions are also pointed out.

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