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arxiv: 1109.4486 · v2 · pith:PMSCMG3Anew · submitted 2011-09-21 · ❄️ cond-mat.soft · cond-mat.stat-mech· physics.chem-ph

Communication: Inferring the equation of state of a metastable hard-sphere fluid from the equation of state of a hard-sphere mixture at high densities

classification ❄️ cond-mat.soft cond-mat.stat-mechphysics.chem-ph
keywords equationhard-spherestatehighmixturedensitiesfluidmetastable
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A possible approximate route to obtain the equation of state of the monodisperse hard-sphere system in the metastable fluid region from the knowledge of the equation of state of a hard-sphere mixture at high densities is discussed. The proposal is illustrated by using recent Monte Carlo simulation data for the pressure of a binary mixture. It is further shown to exhibit high internal consistency.

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