The Electric Double Layer Structure Around Charged Spherical Interfaces
classification
❄️ cond-mat.soft
cond-mat.mes-hallcond-mat.mtrl-sci
keywords
sphericalsolutionanalyticalapplicabilityapproximatearoundchargeddemonstrated
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We derive a formally simple approximate analytical solution to the Poisson-Boltzmann equation for the spherical system via a geometric mapping. Its regime of applicability in the parameter space of the spherical radius and the surface potential is determined, and its superiority over the linearized solution is demonstrated.
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