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arxiv: 1701.06998 · v1 · pith:TGDZ5HIInew · submitted 2017-01-24 · ❄️ cond-mat.soft · cond-mat.stat-mech· physics.chem-ph

Wetting in the presence of the electric field: The classical density functional theory study for a model system

classification ❄️ cond-mat.soft cond-mat.stat-mechphysics.chem-ph
keywords fieldelectricanglecontactfunctionalmodelpresencetheory
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We discuss the effect of an external electric field on the wetting of a solid surface by liquid. To this end, we use a model of the two-level-atom fluid for which the changes in interatomic interactions due to the presence of the field can be found using quantum-mechanical perturbation theory. Constructing the grand potential functional, we perform the standard calculations of Young's equilibrium contact angle. The switching on of the electric field $|{\bf {E}}| > 0$ may increase noticeably the contact angle $\theta$.

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