Suspensions of small ultra-soft colloids remain liquids in overcrowded conditions
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Concentrated suspensions of small ultra-soft colloids (ultra-low crosslinked microgels) are investigated with scattering and steady shear rheology to capture their equilibrium dynamics. The suspensions lack dynamic arrest, although the slow relaxation time $\tau_2$ follows exponential growth with increasing generalized packing fraction, $\zeta$. The zero-shear viscosity grows weakly with $\zeta$, and never diverges in contrast to other soft glass formers, e.g.~star-polymers, microgels, green particles. Their high compressibility allows these ultra-soft spheres to diffuse even in overcrowded environments.
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Cited by 1 Pith paper
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Unexpected Behavior of Ultra-Low-Crosslinked Microgels in Crowded Conditions
Ultra-low-crosslinked microgels interpenetrate without faceting or dynamical arrest at high densities, establishing them as a distinct class dominated by polymeric rather than colloidal degrees of freedom.
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