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arxiv: cond-mat/9909144 · v2 · submitted 1999-09-10 · ❄️ cond-mat.stat-mech · physics.chem-ph· quant-ph

A simple semiclassical approach to Kramers' problem

classification ❄️ cond-mat.stat-mech physics.chem-phquant-ph
keywords equationkramerssemiclassicalapproachbrowniancalculatecorrectiondescribes
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We show that Wigner-Leggett-Caldeira equation for Wigner phase space distribution function which describes the quantum Brownian motion of a particle in a force field in a high temerature, Ohmic environment can be identified as a semiclassical version of Kramers' equation. Based on an expansion in powers of $\hbar$ we solve this equation to calculate the semiclassical correction to Kramers' rate.

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