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arxiv 1401.0047 v3 pith:DKUFHCYN submitted 2013-12-30 cond-mat.mes-hall cond-mat.mtrl-sci

Valley depolarization due to inter- and intra-valley electron-hole exchange interactions in monolayer MoS₂

classification cond-mat.mes-hall cond-mat.mtrl-sci
keywords exchangevalleyinteractioncausedepolarizationelectron-holeexcitoninter-valley
verification ladder T0 review T1 audit T2 compute T3 formal T4 reserved
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We investigate the valley depolarization due to the electron-hole exchange interaction in monolayer MoS$_{2}$. Both the long- and short-range parts of the intra- and inter-valley electron-hole exchange interactions are calculated. We find that both the long- and short-range exchange interactions can cause the inter- and intra-valley bright exciton transitions. With the intra-valley bright exciton transition channel nearly forbidden due to the large splitting of the valence bands, the inter-valley channel due to the exchange interaction can cause the valley depolarization efficiently by the Maialle-Silva-Sham mechanism [Phys. Rev. B {\bf 47}, 15776 (1993)]. With only the long-range exchange interaction, the calculations show good agreement with the recent valley polarization experiments, including the time-resolved valley polarization measurement, the pump-probe experiment and the steady-state PL polarization measurement. We further show that for the A-exciton with large (small) center-of-mass momentum, the long-range exchange interaction can cause the {\em fast} ({\em slow}) inter-valley exciton transition.

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  1. Unveiling the Spin-Valley Structure of Dipolar Exciton Ladders in R-stacked WSe$_2$/WS$_2$ Moir\'e Heterobilayers

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    Helicity-resolved magneto-photoluminescence reveals that the unequal spacing of the dipolar exciton ladder in R-stacked WSe₂/WS₂ arises from triplet and singlet spin-valley two-exciton states, not simple occupation-nu...