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Understanding and modeling polymers: The challenge of multiple scales

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arxiv 2212.08945 v1 pith:FZXNQRUU submitted 2022-12-17 physics.chem-ph cond-mat.soft

Understanding and modeling polymers: The challenge of multiple scales

classification physics.chem-ph cond-mat.soft
keywords scalespolymerpolymersdifferentmaterialsmultiscalesystemsthey
verification ladder T0 review T1 audit T2 compute T3 formal T4 reserved
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Polymer materials have the characteristic feature that they are multiscale systems by definition. Already the description of a single molecules involves a multitude of different scales, and cooperative processes in polymer assemblies are governed by the interplay of these scales. Polymers have been among the first materials for which systematic multiscale techniques were developed, yet they continue to present extraordinary challenges for modellers. In this perspective, we review popular models that are used to describe polymers on different scales and discuss scale bridging strategies such as static and dynamic coarse-graining methods and multiresolution approaches. We close with a list of hard problems which still need to be solved in order to gain a comprehensive quantitative understanding of polymer systems on all scales.

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