Aerosols are not Spherical Cows: Using Discrete Dipole Approximation to Model the Properties of Fractal Particles

The optical properties of particulate-matter aerosols, within the context of exoplanet and brown dwarf atmospheres, are compared using three different models: Mie theory, Modified Mean Field (MMF) Theory, and Discrete Dipole Approximation (DDA). Previous results have demonstrated that fractal haze particles (MMF and DDA) absorb much less long-wavelength radiation than their spherical counterparts (Mie), however it is shown here that the opposite can also be true if a more varying refractive index profile is used. Additionally, it is demonstrated that absorption and scattering cross-sections, as well as the asymmetry parameter, are underestimated if Mie theory is used. Although DDA can be used to obtain more accurate results, it is known to be much more computationally intensive; to avoid this, the use of low-resolution aerosol models is explored, which could dramatically speed up the process of obtaining accurate computations of optical cross-sections within a certain parameter space. The validity of DDA is probed for wavelengths of interest for observations of aerosols within exoplanet and brown dwarf atmospheres (0.2 to 15 micrometres). Finally, novel code is presented to compare the results of Mie, MMF and DDA theories (CORAL: Comparison Of Radiative AnaLyses), as well as to increase and decrease the resolution of DDA shape files accordingly (SPHERIFY). Both codes can be applied to a range of other interesting astrophysical environments in addition to exoplanet atmospheres, for example dust grains within protoplanetary disks.