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arxiv 2012.15328 v2 pith:436LLTK3 submitted 2020-12-30 cond-mat.mtrl-sci

Direct measurement of key exciton properties: energy, dynamics and spatial distribution of the wave function

classification cond-mat.mtrl-sci
keywords excitonexcitonspropertiesfunctionbeenbrightdistributionenergy
verification ladder T0 review T1 audit T2 compute T3 formal T4 reserved
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Excitons, Coulomb-bound electron-hole pairs, are the fundamental excitations governing the optoelectronic properties of semiconductors. While optical signatures of excitons have been studied extensively, experimental access to the excitonic wave function itself has been elusive. Using multidimensional photoemission spectroscopy, we present a momentum-, energy- and time-resolved perspective on excitons in the layered semiconductor WSe$_2$. By tuning the excitation wavelength, we determine the energy-momentum signature of bright exciton formation and its difference from conventional single-particle excited states. The multidimensional data allows to retrieve fundamental exciton properties like the binding energy and the exciton-lattice coupling and to reconstruct the real-space excitonic distribution function via Fourier transform. All quantities are in excellent agreement with microscopic calculations. Our approach provides a full characterization of the exciton properties and is applicable to bright and dark excitons in semiconducting materials, heterostructures and devices.

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  2. Influence of excitation energy on microscopic quantum pathways for ultrafast charge transfer in van der Waals heterostructures

    cond-mat.mes-hall 2025-03 unverdicted novelty 5.0

    Higher-energy excitation at the C-exciton resonance accelerates interlayer hole transfer in WS2-graphene by opening an additional efficient channel enabled by elevated carrier temperatures.