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arxiv 1101.5670 v1 pith:5TCCS5EP submitted 2011-01-29 cond-mat.supr-con cond-mat.mtrl-sci

Crystal structure, physical properties and superconductivity in A_(x)Fe₂Se₂ single crystals

classification cond-mat.supr-con cond-mat.mtrl-sci
keywords superconductivitycrystalssingleobservedresistivityarisecrystalfese
verification ladder T0 review T1 audit T2 compute T3 formal T4 reserved
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We studied the correlation among structure and transport properties and superconductivity in the different $A_x$Fe$_2$Se$_2$ single crystals ($A$ = K, Rb, and Cs). Two sets of (00$l$) reflections are observed in the X-ray single crystal diffraction patterns, and arise from the intrinsic inhomogeneous distribution of the intercalated alkali atoms. The occurrence of superconductivity is closely related to the {\sl c}-axis lattice constant, and the $A$ content is crucial to superconductivity. The hump observed in resistivity seems to be irrelevant to superconductivity. There exist many deficiencies within the FeSe layers in $A_x$Fe$_2$Se$_2$, while their $T_{\rm c}$ does not change so much. In this sense, superconductivity is robust to the Fe and Se vacancies. Very high resistivity in the normal state should arise from such defects in the conducting FeSe layers. $A_x$Fe$_2$Se$_2$ ($A$ = K, Rb, and Cs) single crystals show the same susceptibility behavior in the normal state, and no anomaly is observed in susceptibility at the hump temperature in resistivity. The clear jump in specific heat for Rb$_x$Fe$_2$Se$_2$ and K$_x$Fe$_2$Se$_2$ single crystals shows the good bulk superconductivity in these crystals.

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