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Direct Route to Thermodynamic Uncertainty Relations and Their Saturation

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arxiv 2208.06402 v4 pith:6AW66JQL submitted 2022-08-12 cond-mat.stat-mech math-phmath.MPmath.PR

classification cond-mat.stat-mechmath-phmath.MPmath.PR
keywords directthermodynamictursallowsdynamicsproofrelationstransient
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Thermodynamic uncertainty relations (TURs) bound the dissipation in non-equilibrium systems from below by fluctuations of an observed current. Contrasting the elaborate techniques employed in existing proofs, we here prove TURs directly from the Langevin equation. This establishes the TUR as an inherent property of overdamped stochastic equations of motion. In addition, we extend the transient TUR to currents and densities with explicit time-dependence. By including current-density correlations we, moreover, derive a new sharpened TUR for transient dynamics. Our arguably simplest and most direct proof, together with the new generalizations, allows us to systematically determine conditions under which the different TURs saturate and thus allows for a more accurate thermodynamic inference. Finally we outline the direct proof also for Markov jump dynamics.

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  1. Experimentally accessible measurement of irreversibility in stochastic systems by categorizing single-molecule displacements

    cond-mat.stat-mech 2025-11 conditional novelty 6.0 of 10

    Displacements grouped by starting and ending location yield a model-free Kullback-Leibler measure of irreversibility that bounds entropy production and can be measured from single-molecule data.

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