Symmetries, correlation functions, and entanglement of general quantum Motzkin spin-chains

Motzkin spin-chains, which include 'colorless' (integer spin $s=1$) and 'colorful' ($s \geq 2$) variants, are one-dimensional (1D) local integer spin models notable for their lack of a conformal field theory (CFT) description of their low-energy physics, despite being gapless. The colorful variants are particularly unusual, as they exhibit power-law violation of the area-law of entanglement entropy (as $\sqrt{n}$ in system size $n$), rather than a logarithmic violation as seen in a CFT. In this work, we analytically discover several unique properties of these models, potentially suggesting a new universality class for their low-energy physics. We identify a complex structure of symmetries and unexpected scaling behavior in spin-spin correlations, which deviate from known 1D universality classes. Specifically, the $s=1$ chain exhibits $U(1)$ spontaneous symmetry breaking and ferromagnetic order. Meanwhile, the $s \geq 2$ chains do not appear to spontaneously break any symmetries, but display quasi-long-range algebraic order with power-law decaying correlations, inconsistent with standard Berezinskii-Kosterlitz-Thouless (BKT) critical exponents. We also derive exact asymptotic scaling expressions for entanglement measures in both colorless and colorful chains, generalizing previous results of Movassagh [J. Math Phys. (2017)], while providing benchmarks for potential quantum simulation experiments. The combination of hardness of classically simulating such systems along with the analytical tractability of their ground state properties position Motzkin spin chains as intriguing candidates for exploring quantum computational advantage in simulating many-body physics.