REVIEW 3 major objections 4 minor 1 cited by
Chiral anomaly and internode scatterings in multifold semimetals
T0 review · 3 major / 4 minor · reviewed 2026-08-12 · deepseek-v4-flash
Pith's one-line read A generic Boltzmann formula yields chiral-conductivity tensors for multifold semimetals.
desk verdict Useful first formulas for multifold internode-scattering chiral conductivity, but the numerical prefactors depend on an underived global-equilibration convention and should be treated as conditional. read the letter →
The pith
A machine-rendered reading of the paper's core claim, the machinery that carries it, and where it could break.
The reading
What carries the argument
The carrying object is the semiclassical Boltzmann equation with Berry curvature and orbital magnetic moment corrections, solved in linear response in the relaxation-time approximation with two relaxation times: $\tau$ for intranode scattering and $\tau_G$ for internode scattering. The new ingredient is a global-equilibrium condition under which internode scattering drives each node's local chemical potential toward the mean $\mu_G = (\mu_\chi + \mu_{-\chi})/2$, together with the charge-conservation constraint $\rho_\chi \delta\mu_\chi = -\rho_{-\chi} \delta\mu_{-\chi}$. This determines $\delta\mu_\chi$ self-consistently and, after an expansion to order $B^2$, produces the factorized conductivity formula Eq. (10).
What would settle it
Measure the longitudinal magnetoconductance in a chiral crystal hosting a conjugate triple-point pair or a triple-point/double-Weyl pair in the nonquantizing field regime; the coefficient of $B^2$ must scale as $1/E_F^2$ with the exact prefactors of Eqs. (21) and (23) once $\tau$ and $\tau_G$ are extracted independently. A different field scaling, or a prefactor that does not match the node-specific band structure, would rule out the formula.
Extended reading notes
Core claim
The paper's central claim is that Eq. (10) gives the generic internode-scattering contribution to the chiral conductivity for arbitrary multifold nodes, with the leading nontrivial term quadratic in the magnetic field. For a node of chirality $\chi$ and band $s$, the conductivity tensor takes the form $(\sigma_s^{\chi,\mathrm{inter}})_{ij} = e^2 [\tau_G \rho^{(0)}_{-\chi} - \tau \rho^{(0)}_G] \Upsilon_i^{\chi,s} I_j^{\chi,1} / (\rho^{(0)}_G \rho^{(0)}_\chi) + O(B^3)$. This reduces to simple tensor forms for a conjugate pair of triple-point nodes, for a triple-point node paired with a double Weyl node, and for a Rarita-Schwinger-Weyl node paired with a double triple-point node, producing explicit coefficients such as $\sigma_{ij} = 49 e^4 v_0^3 (\tau_G - \tau) B_i B_j / (72 \pi^2 E_F^2)$ for the conjugate triple-point pair.
Load-bearing premise
The predictions depend on assuming one momentum-independent internode relaxation time $\tau_G$ that is the same for all bands at both nodes, and on the choice that internode scattering relaxes both nodes toward their average chemical potential; if either assumption fails, the $B^2$ form survives but the quoted prefactors change.
Editorial extensions
If this is right
- In the nonquantizing regime, the chiral-anomaly magnetoconductance of multifold nodal semimetals is quadratic in $B$, with coefficients set by the Berry curvature and orbital magnetic moment of every participating band.
- The same-spin conjugate triple-point pair has a distinct prefactor, $49 e^4 v_0^3 (\tau_G - \tau) B_i B_j / (72 \pi^2 E_F^2)$, showing that multifold nodes do not simply inherit the Weyl-node coefficient.
- For mixed pseudospin pairs, the total magnetoconductance receives contributions from both nodes with different Fermi velocities and densities of states, as in Eqs. (23) and (27), so the observable encodes the asymmetry between the two nodes.
- For the Rarita-Schwinger-Weyl node, the internode-scattering current is identical for the $s=1/2$ and $s=3/2$ bands, so the band labels do not enter separately in the observable.
Reading between the lines
- The derivation is restricted to dispersions that depend only on $|k_x|$, $|k_y|$, $|k_z|$; extending Eq. (10) to tilted or anisotropic nodes would likely introduce direction-dependent prefactors beyond the $B_i B_j$ structure.
- If the global-equilibration rule is replaced by relaxation toward the conjugate node's chemical potential, the same $B^2$ form should hold but the numerical coefficients shift, so a measurement can in principle select between the two equilibration pictures.
- Because the prefactors depend on $\tau_G - \tau$ and on the Fermi velocities, future measurements on CoSi-type and SrGePt-type materials could turn negative magnetoresistance data into estimates of the internode scattering rate.
Editorial analysis
A structured set of objections, weighed in public.
Referee Report
Summary. The paper derives a semiclassical Boltzmann expression for the internode-scattering contribution to the chiral conductivity of a pair of conjugate multifold nodal points. The central object is Eq. (10), a B^2 magnetoconductance expressed in terms of the densities of states and Berry-curvature/OMM integrals; specialized formulas are given for Weyl, triple-point, and Rarita-Schwinger-Weyl nodes, including cases in which the two conjugate nodes carry different pseudospin representations. The paper claims these are the first explicit internode-scattering chiral-conductivity expressions for multifold semimetals.
Significance. If Eq. (10) is correct, the paper fills a concrete gap left by the phenomenological treatment of Ref. [8]. It solves the chemical-potential imbalance self-consistently with charge conservation, and the Delta=0 Weyl limit has the expected (tau_G - tau) B^2 structure. The explicit coefficients for triple-point and Rarita-Schwinger-Weyl nodes are new and could, in principle, be compared with experiments on CoSi and SrGePt-family materials. That said, the numerical content is tied to the relaxation-time convention and to an algebraic simplification in Appendix B that appears to alter the final coefficients.
major comments (3)
- [II.B, Appendix A2, Eq. (A13)] The choice mu_G = (mu_chi + mu_-chi)/2 as the global-equilibration target is a model assumption, not derived from a scattering kernel. The alternative target mu_-chi used in Refs. [35,73] is equally natural on physical grounds, since internode scattering transfers carriers from one node to the other, and the paper itself states in Sec. II.B that the mu_G rule is adopted only because it is 'more reasonable.' Because the self-consistent equations (A24)-(A26) and every prefactor in Eqs. (16), (17), (21), (22), (23), and (27) inherit this target, the headline numerical coefficients are convention-dependent. The authors should either derive the internode collision term from a microscopic Golden-Rule calculation or present the results under both the mu_G and mu_-chi conventions and quantify the difference.
- [Appendix B, Eq. (B8)] Equation (B8) does not follow from Eq. (B3). Writing F = -f'(epsilon), the OMM combination in Eq. (B3) is u_j F + eta v_j (-f'') = partial_j(eta F), whose integral over d^3k vanishes. Thus, at order B, the u_j and eta terms cancel, and I^{chi,1}_j should reduce to the Berry-curvature term integral e Omega . v B_j (-f') alone. The retention of the (m)_j (v)_j f'' term in Eq. (B8), and correspondingly in Eq. (10) through Upsilon^{chi,s}_j, appears to overcount the OMM contribution. This will change all numerical coefficients in Sec. III and must be rechecked and the integrals recomputed.
- [Appendix A2] The derivation assumes a single momentum-independent internode-scattering time tau_G applied identically to every band at both nodes. This is stated explicitly in Appendix A2, but for the mixed-pseudospin cases of Eqs. (23) and (27), where the two nodes have different degeneracies, Berry curvatures, and Fermi velocities, a band-independent tau_G is an uncontrolled assumption. Every numerical coefficient in those equations depends on it; the authors should at least discuss the sensitivity to this assumption or show how tau_G would be band-resolved in a more microscopic treatment.
minor comments (4)
- [Abstract and Introduction] There are several typographical errors, including 'thechiral anomaly' in the abstract and 'Nielson' for Nielsen in the Introduction; these should be corrected.
- [II.B] The statement that the choice of global-equilibration target leads only to 'minute quantitative differences' is not substantiated. Since the authors have the formulas under both conventions, they should show the comparison explicitly or remove the claim.
- [III.A, Eqs. (17)] The notation in Eqs. (17), (22), and (27) would be clearer if the density of states rho_chi^(0) for the Delta > 0 cases were defined explicitly in the main text rather than only in Appendix B.
- [Eq. (10)] The subscript s on sigma^{chi,inter}_s is potentially confusing because s is summed over in I^{chi,1}_j; a sentence explaining that s labels the band whose current is computed would help.
Circularity Check
No significant circularity: the chiral-conductivity formula is derived from the Boltzmann equation with explicit, acknowledged assumptions and is not defined in terms of its own predictions.
full rationale
The central result, Eq. (10), is obtained through a self-contained derivation in Sec. II A and Appendices A2 and B. The internode-scattering conductivity follows from the linearized Boltzmann equation with the collision term I_inter = -(f - f_G)/tau_G, the charge-conservation constraint rho_chi delta_mu_chi = -rho_-chi delta_mu_-chi, and a systematic expansion of the density of states and current vertex in powers of B. No quantity in Eq. (10) is fitted to the conductivity it predicts: tau and tau_G are phenomenological relaxation times that appear linearly and are not claimed to be derived, while the numerical prefactors in Eqs. (16), (21), (22), (23), and (27) are obtained by explicit momentum integrals of the Berry curvature and orbital magnetic moment of the stated Hamiltonians. The choice of global-equilibrium target mu_G = (mu_chi + mu_-chi)/2 is an explicit modeling assumption, acknowledged in Sec. II B as an alternative to the convention of Refs. [35, 73]; although that choice can affect the prefactors, it is not a circular redefinition because the paper does not present the target as derived from the output conductivity. The self-citations to the author's earlier works, e.g., Refs. [26, 27, 43, 44, 46, 47, 48], are for standard Boltzmann solution techniques that are reproduced in the appendices; they are not load-bearing for the new result. The WSM limit is compared with, not replaced by, earlier papers, and the multifold results are new integrations over the same formalism. Thus the derivation is self-contained and no step reduces to its own input by construction.
Assumptions & free parameters
free parameters (3)
- Intranode relaxation time τ
- Internode relaxation time τ_G
- Node energy offset Δ
assumptions (6)
- domain assumption Nielsen-Ninomiya theorem: the sum of monopole charges over the entire Brillouin zone vanishes, so nodes appear in χ = ±1 pairs
- standard math Semiclassical equations of motion with Berry curvature and OMM corrections, Eq. (A3), including the e(E·B)Ω term
- domain assumption Relaxation-time approximation with momentum-independent collision integrals, I_coll = -δf/τ
- ad hoc to paper Local equilibrium at each node with chemical potential μ_χ, relaxing globally toward μ_G = (μ_χ + μ_{-χ})/2
- domain assumption Charge conservation across the two nodes: ρ_χ δμ_χ = -ρ_{-χ} δμ_{-χ}
- domain assumption Isotropic linear-dispersion k·p Hamiltonians for WSM, TSM, and RSW nodes, with the stated Berry curvature and OMM (Eqs. 12, 15, 18, 20, 24, 26)
Cite this review
Pith. "Pith review of Chiral anomaly and internode scatterings in multifold semimetals." pith.science (2026). https://pith.science/paper/CQ325YNI
@misc{pith2026241118434,
author = {Pith},
title = {Pith review of: Chiral anomaly and internode scatterings in multifold semimetals},
year = {2026},
howpublished = {\url{https://pith.science/paper/CQ325YNI}},
note = {Machine review of arXiv:2411.18434}
}
abstract
In our quest to unravel the topological properties of nodal points in three-dimensional semimetals, one hallmark property which warrants our attention is the \textit{chiral anomaly}. In the Brillouin zone (BZ), the sign of the Berry-curvature field's monopole charge is referred to as the chirality ($\chi$) of the node, leading to the notion of chiral quasiparticles sourcing chiral currents, induced by internode scatterings proportional to the chiral anomaly. Here, we derive the generic form of the chiral conductivity when we have multifold nodes. Since the sum of all the monopole charges in the BZ is constrained to vanish, the nodes appear in pairs of $\chi =\pm 1$. Hence, the presence of band-crossing degeneracies of order higher than two make it possible to have two distinct scenarios: the pair of conjugate nodes in question comprise bands of (1) the same pseudospin variety and exhibiting Berry-curvature profiles differing by an overall factor of $\chi$, or (2) two distinct pseudospin representations. Covering these two possibilities, we apply our derived formula to semimetals harbouring triple-point (threefold-degenerate) and Rarita-Schwinger-Weyl (fourfold-degenerate) nodes, and show the resulting expressions for the conductivity featuring the chiral anomaly.
Figures
Forward citations
Cited by 1 Pith paper
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Reflections of topological properties in the planar-Hall response for semimetals carrying pseudospin-1 quantum numbers
Closed-form electric, thermoelectric, and thermal conductivities up to third order in magnetic field are derived for pseudospin-1 triple-point semimetals, including out-of-plane anomalous Hall and Lorentz-force currents.
Reference graph
Works this paper leans on
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[8]
Solution in the presence of internode scattering We now discuss how to include internode scatterings in a relaxation-time approximation, where we treat the internode- scattering timeτ G as a phenomenological constant (analogous toτ). To start with, let us assume that initially, in the infinite past (denoted by timet=−∞), a pair of conjugate nodes had the ...
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[1]
Solution in the absence of internode scattering 8
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[2]
Solution in the presence of internode scattering 9 B. Terms expanded upto orderB 2 11 C. Useful integrals 13 References 13 I. INTRODUCTION There have been continuous efforts, both on the theoretical and experimental fronts, for unravelling the multifaceted exotic properties of three-dimensional (3d) semimetals, which harbour symmetry-protected band-crossi...
arXiv 2025
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[3]
+ 2 ∆v3 0 (2E F + ∆) −τ # at the Γ-point and 2× σ−1,inter s=1 ij = 4e 4 ˜v3 0 Bi Bj 9π 2 (EF + ∆)2 2E 2 F ˜v3 0 τG E2 F (˜v3 0 + 2v 3
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[4]
Summing over the two nodes, we get the total value as σ1,inter s=1 ij + 2× σ−1,inter s=1 ij
+ 2 ∆v3 0 (2E F + ∆) −τ at theR-point.(23) Here,v 0 and ˜v0 denote the group velocities of the pseudospin-1 (for TSM) and pseudospin-1/2 (for WSM) quasiparticles, respectively. Summing over the two nodes, we get the total value as σ1,inter s=1 ij + 2× σ−1,inter s=1 ij . C. Rarita-Schwinger-W eyl semimetal The explicit form of the Hamiltonian for a single ...
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[5]
+ 27 ∆v3 0 (2E F + ∆) −τ # at the Γ-point and 2× σ−1,inter s=1 ij = 49e 4 ˜v3 0 Bi Bj 36π 2 (EF + ∆)2 224E 2 F ˜v3 0 τG E2 F (112 ˜v3 0 + 27v 3
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[6]
Here,v 0 and ˜v0 denote the group velocities of the pseudospin-3/2 (for the RSW node) and pseudospin-1 (for TSM) quasiparticles, respectively
+ 27 ∆v3 0 (2E F + ∆) −τ at theR-point.(27) We find that the values for both the RSW bands (withs= 1/2 ands= 3/2) are the same, as expected. Here,v 0 and ˜v0 denote the group velocities of the pseudospin-3/2 (for the RSW node) and pseudospin-1 (for TSM) quasiparticles, respectively. Summing over the two nodes, the total value is obtained from σ1,inter 1/2...
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[7]
smallness parameter
Solution in the absence of internode scattering The Fermi-Dirac distribution function, f (0) s,χ(r,k)≡f (0) ξχ s (k), µχ, T(r) = 1 1 + exp h ξχ s (k)−µχ T(r) i ,(A5) describes a local equilibrium situation at the subsystem centred at positionr, at the local temperatureT(r), and with a spatially uniform chemical potentialµ χ. We consider the situation wher...
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