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Recently developed large language models (LLMs) have been shown to perform remarkably well on a wide range of language understanding tasks. But, can they really "reason" over the natural language? This question has been receiving significant research attention and many reasoning skills such as commonsense, numerical, and qualitative have been studied. However, the crucial skill pertaining to 'logical reasoning' has remained underexplored. Existing work investigating this reasoning ability of LLMs has focused only on a couple of inference rules (such as modus ponens and modus tollens) of propositional and first-order logic. Addressing the above limitation, we comprehensively evaluate the logical reasoning ability of LLMs on 25 different reasoning patterns spanning over propositional, first-order, and non-monotonic logics. To enable systematic evaluation, we introduce LogicBench, a natural language question-answering dataset focusing on the use of a single inference rule. We conduct detailed analysis with a range of LLMs such as GPT-4, ChatGPT, Gemini, Llama-2, and Mistral using chain-of-thought prompting. Experimental results show that existing LLMs do not fare well on LogicBench; especially, they struggle with instances involving complex reasoning and negations. Furthermore, they sometimes overlook contextual information necessary for reasoning to arrive at the correct conclusion. We believe that our work and findings facilitate future research for evaluating and enhancing the logical reasoning ability of LLMs. Data and code are available at https://github.com/Mihir3009/LogicBench.